Titan’s chemical orgies

Titan probably smells weird. It looks like a ball of dirt. It has ponds and streams of liquid ethane and methane and lakes of the two ethanes, with nitrogen bubbling up in large patches, near its poles. It has clouds of hydrocarbons raining down more methane. And like the water cycle on Earth, Titan has a methane cycle. Its atmosphere is a stifling billow of (mostly) nitrogen. Its surface temperature often dips below -180º C, and the Sun is as bright in its sky as our moon is in ours. In all, Titan is a dank orgy of organic chemistries playing out at the size of a small planet. And it smells weird – like gasoline. All the time.

But it is also beautiful. Titan is the only other object in the Solar System known to have bodies of liquid something flowing on its surface. It has a thick atmosphere and seasons. Its methane cycle signifies a mature and stable resource recycling system, just the way a functional household allows you to have routines. Yes, it’s cold and apparently desolate, but Titan can’t help these things. Water would freeze on its surface but the Saturnian moon has made do with what wouldn’t, and it has a singularly fascinating surface chemistry to show for it. Titan has been one of the more unique moons ever found.

And new observations and studies of the moon only make it more unique. This week, scientists from the Georgia Institute of Technology reported Titan possibly has dunes of tar that, once formed, stay in formation because their ionised particles cling together. The scientists stuck naphthalene and biphenyl – two organic compounds thought to exist on Titan’s surface – into a tumbler, tumbled it around for about 20 minutes in a nitrogen chamber and then emptied it. According to a Georgia Tech press release, 2-5% of the mixture lumped up.

The idea of tarry sands is not new. The Cassini probe studying the Saturn system found strange, parallel dunes near Titan’s equator in 2006, over a hundred metres tall. Soon after, scientists were thinking about ‘sediment cohesiveness’, the tendency of certain particles to stick together because of weak but persistent static charges, to explain the dunes. These charges are much weaker among sand particles and volcanic ash on Earth. Then again, in a 2009 paper in Nature Geoscience – the same journal the Georgia Tech study was published in – planetary geologists showed that longitudinal dunes, as they were called, were known to form in the Qaidam Basin in China. A note accompanying the paper explained:

More recent models for linear dune formation are centred on two main scenarios for formation and perpetuation. Winds from two alternating directions, separated by a wide angle, result in the formation of dunes whose long axis falls somewhere between the two wind directions. Alternatively, winds blowing from a single direction along a dune surface that has been stabilized in some way, for example by vegetation, an obstacle or sediment cohesiveness, can produce the same dune form.

That the Georgia Tech study affirmed the latter possibility doesn’t mean the former has been ruled out. Scientists have shown that bi-directional winds are possible on Titan, where wind blows in one direction over a desert and then shifts by 120º and blows over the same patch, forming a longitudinal dune. One of the Georgia Tech study’s novelties is in finding a way for the dune’s particles to stick together. Previous studies couldn’t confirm this was possible because the dunes mostly occur near Titan’s equator, where the weather is relatively much drier than at the poles, where mud-like clumps can form and hold their shape.

The other novelty is in using their naphthalene-biphenyl model to explain why the longitudinal dunes are also facing away from the wind. As one of the study’s authors told New Scientist, “The winds are moving one way and the sediments are moving the other way.” This is because the longitudinal dunes accrue on existing dunes and elongate themselves backwards. And once they do form, more naphthalene and biphenyl grains stick on them thanks to the static produced by them rubbing against each other. Only storms can budge them then.

The Georgia Tech group also writes in its paper that infrared and microwave observations suggest the dune’s constituent particles don’t become available through the erosion of nearby features. Instead, the particles become available out of Titan’s atmosphere, in the form of ‘haze particles’. They write: “[Frictional] charging provides an efficient process for the aggregation of simple aromatic hydrocarbons, and may serve as a mechanism for the formation of dune grains with diameters of several hundred micrometers from micrometer-sized haze particles.”

A big-picture implication is that Titan’s surface features are shaped by agents that are almost powerless on Earth. In other words, Titan doesn’t just smell weird; it’s also sticky. Despite the moon’s being similar to Earth in many ways, there are still drastic differences arising from small mismatches, mismatches we’d think wouldn’t make a difference. They remind us of the conditions we take for granted at home that are friendly to life – and of the conditions in which we can still dream of the possibility of life. Again, studies (described here and here) have shown this is possible. One has even warned us that Titanic lifeforms, if they exist, would smell nowhere as good as their name at all.

Understanding the dunes is a way to understand Titan’s winds. This is important because future missions to the moon envisage wind-blown balloons and cruising gliders.

Featured image: Saturn in the background of Titan, its largest moon. Credit: gsfc/Flickr, CC BY 2.0.

I’d written this post originally for Gaplogs but it got published in The Wire first.